Perfluoroalkylsulfonyl Compounds
Perfluoroalkylsulfonyl compounds, manufactured using electrochemical fluorination techniques, have several unique features such as low surface tension and high chemical and thermal stability. They are widely used as a photo-resistant component in semiconductors, surfactants, anti-static agents, and various kinds of additives. Eco-friendly perfluoroalkylsulfonyl compounds are designed with a view to minimizing the environmental impact while still maintaining their unique features. It is expected that they will be applied in a wide variety of advanced uses as newly developed products for the next generation.
■Main features
Super strong acid (Super acid) | High chemical stability |
---|---|
High thermal stability | Non-PFOS structure |
■Super strong acid (Super acid)
As organic super strong acids (or their salts) derived from their structures of perfluoroalkylsulfonyl group, they are suitable for photo acid generators in photoresist. It is expected that semiconductor-processing technology will be developed for the next generation (photolithography). Meanwhile, they are also valuable as strong acid catalysts in organic synthesis.
■High chemical stability
Even under the severe-use conditions of a strong acid or a strong base, they are stable and demonstrate their unique features such as low surface tension.
■High thermal stability
Since these salts do not decompose under high temperatures of 250 to 300℃, they can be used as additives for resin molding or in modification processes.
■Non-PFOS structure
This does not include the PFOS (C8F17SO2-; Perfluoroalkylsulfonyl) structure, which has been identified to have the potential to accumulate in the environment and in human bodies.
■Product information
Product name | Chemical formula | Chemical name | Morecular weight | Appearance | Physical properties |
---|---|---|---|---|---|
EF-11 | CF3SO3H | Trifluorometanesulfonic acid (Triflic acid) |
150.07 | Colorless liquid | bp:162℃ |
EF-15 | CF3SO3Li | Lithium trifluoromethanesulfonate (Lithium triflate) | 156.01 | White powder | mp:423℃ |
EF-18 | (CF3SO2)2O | Trifluoromethanesulfonic anhydride (Triflic anhydride) | 282.13 | Colorless liquid | bp:84℃ |
FBSA | C4F9SO3H | Nonafluorobutanesulfonic acid | 300.10 | Colorless liquid | bp:210-212℃ |
KFBS | C4F9SO3K | Nonafluorobutanesulfonic acid potassium salt | 338.19 | White powder | mp:271℃ |
EF-N111S-30 | (CF3SO2)2NH | 30% bis(trifluoromethanesulfonyl)imide aqueous solution | 281.14 | Colorless liquid | - |
EF-N115 | (CF3SO2)2NLi | Lithium bis(trifluoromethanesulfonyl)imide | 287.08 | White powder | mp:232-234℃ |
EF-N441S-30 | (C4F9SO2)2NH | 30% bis(nonafluorobutanesulfonyl)imide aqueous solution | 581.19 | Colorless liquid | - |
■Applications
Product name | Application |
---|---|
EF-11 | Acid catalyst, Raw material for ionic liquid, Synthetic raw material |
EF-15 | Additive for lithium battery |
EF-18 | Triflating agents for pharma and agrochemical intermediate, Synthetic raw material |
FBSA | Acid catalyst, Raw material for ionic liquid and photo-acid-generator(PAG), Synthetic raw material |
KFBS | Fire retardant for PC resin, Raw material for photo-acid-generator(PAG) |
EF-N111S-30 | Acid catalyst, Raw material for ionic liquid |
EF-N115 | Ionic conductive material, Electrolyte, Raw material for ionic liquid |
EF-N441S-30 | Surfactant, Acid catalyst, Raw material for ionic liquid |
■Legal regulation of countries and region
Product name | CAS No. | Japan | China | Korea | U.S. | EU |
---|---|---|---|---|---|---|
ENCS | IECSC | ECL | TSCA | EINECS | ||
EF-11 | 1493-13-6 | ● | ● | ● | ● | ● |
EF-15 | 33454-82-9 | ● | ● | ● | ● | ● |
EF-18 | 358-23-6 | ● | ● | - | ● | ● |
FBSA | 375-73-5 | - | - | - | ● | ● |
KFBS | 29420-49-3 | ● | ● | ● | ● | ● |
EF-N111S-30 | 82113-65-3 | - | ● | - | ● | - |
EF-N115 | 90076-65-6 | ● | ● | ● | ● | ● |
EF-N441S-30 | 39847-39-7 | - | ● | - | - | - |